No bit problem with the white day lights as long as Octoguard had darkness so you will want to arrange the 30 to give him darkness if you have extra lighting. I don't use other lighting with mercs (the room gets a lot of natural light though) and have had better interactive success (albeit at 11:00 PM) but I can't say it is because I don't add daytime light (you might want to consider keeping the 30 at home). The red light during the day is totally unnecessary, I just leave it on 24/7 (even if I have white/blue lights on the tank - not something I did with O. mercatoris but do have on other tanks) because it reduces yet another electrical appliance (a timer) for the tank. I will warn you that the red light is great for viewing but really, really bad for photography (I have a few unposted photos that make it look like there is a layer of blood (not octo blood because it is not red but almost transparent with a blue cast, you will never see it) globbed at the top of the tank.
I dont have any pics of him, I wish I did. Computer crashed and I lost everything
Yet another reason for keeping an on-line journal
(it also helps with clearer memories
).
Your first octo's daytime activity sounds a lot like O. hummelincki
but vulgaris are, IMO, the smartest of the lot and possibly most inclined to interact with humans (anecdotal from on-line and written text about them interacting with divers). They can be found hunting at all times of the day even though they are listed as crepuscular (early evening and early morning hunters - ATM, Margay seems to think 5:00 is a good time to explore but we are still acclimating). O. briareus reaches that size (smaller mantle than O. vulgaris but longer arms) but a lot of daytime activity is not likely. Hummelincki
can have an arm stretch of about 18" (personal observation but there is a huge sizing difference with this species) but even stretched, it would be unusual to see one with arms that could span more than about 3'. Hummelincki also has eye spots you would have detected and a shorter lifespan so I think your ID call of vulgaris is highly likely.
All that being said, each octopus will have its own personality. There are generalizations that I make but any that I hold firmly will be/have been broken as soon as I mention them too many times